Kinetic Studies of Atom Transfer Radical Polymerisations of Styrene and Chloromethylstyrene with Poly(3-hexyl thiophene) Macroinitiator
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چکیده
منابع مشابه
kinetic study of atom transfer radical polymerization of methyl acrylate with polyvinyl acetate macroinitiator
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Experimental as well as theoretical studies have been carried out with the aim of elucidating the mechanism of the atom transfer radical addition (ATRA) of styrene and carbon tetrachloride with a Tp(x)Cu(NCMe) complex as the catalyst precursor (Tp(x) = hydrotrispyrazolyl-borate ligand). The studies shown herein demonstrate the effect of different variables in the kinetic behavior. A mechanistic...
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A novel nano-initiator containing kojic acid moiety, [5-(benzyloxy)-4-oxo-4H-pyran-2-yl)methyl-2-bromo-2-methylpropanoate was synthesized by the reaction of 5-(benzyloxy)-2-(hydroxymethyl)-4H-pyran-4-one with 2-bromoisobutyryl bromide in triethylamine and used as initiator in the atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate in the presence of Cu(0)/CuCl2and N,N...
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ژورنال
عنوان ژورنال: Advances in Materials Science and Engineering
سال: 2015
ISSN: 1687-8434,1687-8442
DOI: 10.1155/2015/973632